Which compound in each pair has the higher boiling point? acetone or 2-propanol. dimethyl ether or acetaldehyde
Heat of vaporization at boiling point = 330 kJ/kg; Specific heat capacity at 20 °C = 2.26 kJ/kg/K; Dynamic viscosity at 20 °C = 84 mPa s. Used as a plasticizer for 2-hydroxypropyl cellulose resins /1,1'-(propylenedioxy)di-2-propanol/ Kirk-Othmer Encyclopedia of Chemical Technology. 3rd ed., Volumes 1-26. New York, NY: John Wiley and Sons 2- propanol has greater boiling point, because hydrogen bonds between 2-propanol molecules, more energy is required to breake those bonds. Hydrogen bond is an electrostatic attraction between two polar groups that occurs when a hydrogen atom (H), covalently bound to a highly electronegative atom such as flourine (F), oxygen (O) and nitrogen (N The boiling point of 2-propanol is 82.3°C at standard pressure. 71 Explain, in terms of electronegativity differences, why a C O bond is more polar than a C H bond. [1] Answer==>There is a greater electronegativity difference in a C-O bond than in a C-H bond. 2-Propanol, sec-Propyl alcohol, IPA, Isopropanol, Isopropyl alcohol. Linear Formula: (CH 3) 2 CHOH. CAS Number: 67-63-. Molecular Weight: 60.10. Product Comparison Guide. Use the product attributes below to configure the comparison table. (Select up to 3 total.) Select Attribute. Select Attribute. Select Attribute.Average of 38 out of 40 values; Individual data points: Quantity Value Units Method Reference Comment; T fus: 180. ± 20. K: AVG: N/A: Average of 6 values; Individual data points: Quantity Value Units Method Reference Comment; T triple: 171.32: K: N/A: Vasil'ev and Petrov, 1984: Uncertainty assigned by TRC = 0.01 K; TRC: T triple: 171.15: K: N
The boiling point is a rough measure of the amount of energy necessary to separate a liquid molecule from its nearest neighbors. If the molecules interact through hydrogen bonding, a relatively large quantity of energy must be supplied to break those intermolecular attractions. Only then can the molecule escape from the liquid into the gaseous ksGM.